Workbook workbook = new Workbook();
string str="D:\\文件名";
workbook.LoadFromFile(str);
Worksheet sheet = workbook.Worksheets[0];
sheet.Range["B2"].Text = "22323";
//设置打印纸张大小
sheet.PageSetup.PaperSize = PaperSizeType.PaperA4;
//导出
workbook.SaveToFile("D:\\result.xlsx", FileFormat.Version2007);
//打印
workbook.PrintDocument.Print();