东南大学官网计算机工程学院陶军,陶军-厦门大学化学化工学院-优快云博客

这些研究集中在金属有机框架（MOFs）、配位聚合物及其磁性转变现象上，包括温度、光照、溶剂和客体分子的影响导致的结构变化和磁性行为。文章详细探讨了钴、铁、镍等过渡金属离子的单核和多核复合物中的自旋转换、电荷转移、结构重构和客体分子交换等现象，展示了这些材料在气体吸附、分离和磁存储等方面的潜在应用。

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Spin transition and structural transformation in a mononuclear cobalt(II) complex, Guo Ying, Yang Xiu-Long, Wei Rong-Jia, Zheng Lan-Sun, Tao Jun,* Inorg. Chem. 2015, 54(16), 7670-7672.

Coligand and solvent effects on the architectures and spin-crossover properties of (4,4)-connected iron(II) coordination polymers, Wu Xue-Ru, Shi Hai-Yan, Wei Rong-Jia,* Li Jia, Zheng Lan-Sun, Tao Jun,* Inorg. Chem. 2015, 54(8), 3773-3780.

Anionic metal–organic framework for adsorption and separation of light hydrocarbons, Li Jia, Fu Hong-Ru, Zhang Jian, Zheng Lan-Sun, Tao Jun,* Inorg. Chem. 2015, 54(7), 3093-3095.

Synergetic spin crossover and fluorescence in one-dimensional hybrid complexes, Wang Chun-Feng, Li Ren-Fu, Chen Xue-Yuan, Wei Rong-Jia, Zheng Lan-Sun, Tao Jun,* Angew. Chem., Int. Ed. 2015, 54(5), 1574-1577.

Valence tautomeric transitions of three one-dimensional cobalt complexes, Chen Xiang-Yi, Wei Rong-Jia, Zheng Lan-Sun, Tao Jun,* Inorg. Chem. 2014, 53(24), 13212-13219.

Solvent-mediated isomerization of FeII complexes from a 3D 65·8 framework to a 2D 44 rhombus-grid network, Wu Xue-Ru, Yang Xü, Wei Rong-Jia,* Li Jia, Zheng Lan-Sun, Tao Jun,* Cryst. Growth Des. 2014, 14(10), 4891-4894.

A spin canted NiII4-based metal-organic framework with gas sorption properties and high adsorptive selectivity for light hydrocarbons, Li Jia, Guo Ying, Fu Hong-Ru, Zhang Jian, Huang Rong-Bin, Zheng Lan-Sun, Tao Jun,* Chem. Commun. 2014, 50(65), 9161-9164.

Co-ligand and solvent effects on the spin-crossover behaviors of PtS-type porous coordination polymers, Chen Xiang-Yi, Huang Rong-Bin, Zheng Lan-Sun, Tao Jun,* Inorg. Chem. 2014, 53(10), 5246-5252.

Temperature, light and solvent-induced spin transition in a 3D 2-fold interpenetrated PtS-type porous coordination polymer, Chen Xiang-Yi, Shi Hai-Yan, Huang Rong-Bin, Zheng Lan-Sun, Tao Jun,* Chem. Commun. 2013, 49(93), 10977-10979.

A boracite metal–organic framework displaying selective gas sorption and guest-dependent spin-crossover behaviour, Shao Feng, Li Jia, Tong Jia-Ping, Zhang Jian, Chen Ming-Guang, Zheng Zhiping,* Huang Rong-Bin, Zheng Lan-Sun, Tao Jun,* Chem. Commun. 2013, 49(91), 10730-10732.

Four coordination polymers based on identical eight-connected heptanuclear clusters: spin canting, spin glass, antiferromagnetism, and gas adsorption, Li Jia, Li Bao, Huang Peng, Shi Hai-Yan,* Huang Rong-Bin, Zheng Lan-Sun, Tao Jun,* Inorg. Chem. 2013, 52(19), 11573-11579.

Metal-organic frameworks displaying single crystal-to-single crystal transformation through postsynthetic uptake of metal clusters, Li Jia, Huang Peng, Wu Xue-Ru, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Chem. Sci. 2013, 4(8), 3232-3238.

Unidirectional charge transfer in di-cobalt valence tautomeric compound finely tuned by ancillary ligand, Li Bao, Chen Li-Qin, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Inorg. Chem. 2013, 52, 4136-4138.

Magnetic nanosized {MII24}-wheel-based (M = Co, Ni) coordination polymers, Li Jia, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Inorg. Chem. 2012, 51(11), 5988-5990.

Twist angle perturbation on mixed (phthalocyaninato)(porphyrinato)dysprosium(III) double-decker SMMs, Wang Hai-Long, Wang Kang, Tao Jun,* Jiang Jian-Zhuang,* Chem. Commun. 2012, 48(24), 2973-2975.

Polymorphism in spin-crossover systems, Tao Jun,* Wei Rong-Jia, Huang Rong-Bin, Zheng Lan-Sun, Chem. Soc. Rev. 2012, 41(2), 703-737.

Spin-crossover FeII4 squares: two-step complete spin transition and reversible single-crystal-to-single-crystal transformation, Wei Rong-Jia, Huo Qian, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Angew. Chem. Int. Ed. 2011, 50(38), 8940-8943.

Reversible and irreversible vapor-induced guest molecule exchange in spin-crossover compounds, Wei Rong-Jia, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Inorg. Chem. 2011, 50(17), 8553-8564.

Microwave-assisted synthesis of a ferrimagnetic dodecanuclear iron(III) complex with a Fe4(OH)4 cubane core, Tong Jia-Ping, Shao Feng, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Inorg. Chem. 2011, 50(6), 2067-2069.

Making spin-crossover crystals by successive polymorphic transformations, Wei Rong-Jia, Li Bao, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Zheng Zhiping,* Inorg. Chem. 2011, 50(4), 1170-1172.

Temperature-dependent in situ ligand cyclization via C=C coupling and formation of a spin-crossover iron(II) coordination polymer, Yang Feng-Lei, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Inorg. Chem. 2011, 50(3), 911-917.

Thermally induced and photoinduced valence tautomerism in a two-dimensional coordination polymer, Li Bao, Chen Li-Qin, Wei Rong-Jia, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Zheng Zhiping,* Inorg. Chem. 2011, 50(2), 424-426.

In situ C-C coupling and formation of a heptanuclear copper(II) cluster, Tong Jia-Ping, Sun Xiao-Jun, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Inorg. Chem. 2010, 49(4), 1289-1291.

Solvent-induced transformation of single crystals of a spin-crossover (SCO) compound to single crystals with two distinct SCO centers, Li Bao, Wei Rong-Jia, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Zheng Zhiping,* J. Am. Chem. Soc. 2010, 132(5), 1558-1566.

Pressure effects on a spin-crossover monomeric compound [Fe(pmea)(SCN)2] (pmea = bis[(2-pyridyl)methyl]-2-(2-pyridyl)ethylamine), Li Bao, Wei Rong-Jia, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Inorg. Chem. 2010, 49(2), 745-751.

Self-assembly of high-nuclearity copper cages: tricorne Cu21 and saddlelike cyclic Cu16, Bai Yue-Ling, Tangoulis Vassilis,* Huang Rong-Bin, Zheng Lan-Sun, Tao Jun,* Chem. Eur. J. 2009, 15(10), 2377-2383.

The designed assembly of augmented diamond networks from predetermined pentanuclear tetrahedral units, Bai Yue-Ling, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Angew. Chem. Int. Ed. 2008, 47(29), 5344-5347.

The effects of pressure on valence tautomeric transitions of dinuclear cobalt complexes, Li Bao, Yang Feng-Lei, Tao Jun,* Sato Osamu, Huang Rong-Bin, Zheng Lan-Sun, Chem. Commun. 2008, 6019-6021.

Side-effect of ancillary ligand on electron transfer and photodynamics of dinuclear valence tautomeric complex, Li Bao, Tao Jun,* Sun Hao-Ling, Sato Osamu,* Huang Rong-Bin, Zheng Lan-Sun, Chem. Commun. 2008, 2269-2271.

Pressure effects and Mössbauer spectroscopic studies on a 3D mixed-valence iron spin-crossover complex with NiAs topology, Bai Yue-Ling, Tao Jun,* Huang Rong-Bin, Zheng Lan-Sun, Zheng Shao-Liang,* Oshida K., Einaga Yasuaki,* Chem. Commun. 2008, 1753-1755.Research Interest