itoa is not ansi C standard and you should probably avoid it. Here are some roll-your-own implementations if you really want to use it anyway:
http://www.jb.man.ac.uk/~slowe/cpp/itoa.html
If you need in memory string formatting, a better option is to use snprintf. Working from your example:
#include <stdio.h>
#include <stdlib.h>
int main ()
{
int i;
char buffer [33];
printf ("Enter a number: ");
scanf ("%d",&i);
snprintf(buffer, sizeof(buffer), "%d", i);
printf ("decimal: %s\n",buffer);
return 0;
}