First, we will bind data source to drop down list. Set the segment as below.
ddlCatalogName.DataSource = dtCatalogIDs;
ddlCatalogName.DataTextField = "CatalogName";
ddlCatalogName.DataValueField = "CatalogID";
ddlCatalogName.DataBind();
Then add a default value to this drop down list such as "Please select".
// Add default value
ddlCatalogName.Items.Insert(0, new ListItem("------Select------", "0"));
Ok. That's all.